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Malononitrile CAS 109-77-3

Malononitrile is a raw material for the preparation of 2-amino -4, 6-dimethoxypyrimidine and 2-chloro-4, 6-dimethoxypyrimidine. It can be used to produce sulfonylurea herbicides such as bensulfuron-methyl, pyrisulfuron-methyl, etc., and it can also be used to make herbicide bisoxyl, which is used to make diuretic drugs in medicine.
Organic synthetic raw materials. In medicine, it is used to synthesize a series of important drugs such as vitamin B1, methotrexate, and triamterene. Dyes, pesticides and other aspects have important uses. It can also be used as an extractant for gold. China is now mainly used for the production of triamterene, bensulfuron, 1,4,5,8-naphthenic acid, pyrimidine series products.
It is used in pharmaceuticals and is a drug triamterene intermediate
It can be used as a raw material for organic synthesis, a pharmaceutical intermediate and an organic solvent.
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Product Name Malononitrile
Synonyms Dicyanomethane; Propanedinitrile; MDN; Malonitrile; Malonodinitrile; N-(4-Fluorobenzoyl)piperidine; Cyanoacetonitrile
Molecular Formula C3H2N2
Molecular Weight 66.0614
CAS Registry Number 109-77-3
Molecular Structure Malononitrile_78_28
Product Application Utilized in pharmaceuticals as an intermediate for the drug amantadine, and in organic synthesis as an extractant for gold.


Names and Identifiers

Malononitrile, also known as MDN, malonodinitrile, dicyanomethane, 

or other synonyms, is a chemical compound with the CAS number 109-77-3. 

It has the molecular formula C3H2N2 and the molar mass 66.06.

Chemical Properties

It is a colorless crystalline substance that dissolves in water and some organic solvents. 

It has a relative density of 1.1910, a melting point of 32°C, a boiling point of 218-219°C, 

a refractive index of 34.2°C, and a flash point of 112°C. 


Production Usage


It is mainly used as a raw material for organic synthesis, especially for the preparation of 2-amino-4,6-dimethoxypyrimidine and 2-chloro-4,6-dimethoxypyrimidine. 

These compounds can be used to produce sulfonylurea herbicides, 

such as bensulfuron-methyl and pyrisulfuron-methyl, and diuretic drugs, such as bisoxyl. 

It can also be used to synthesize important drugs, such as vitamin B1, methotrexate, 

and triamterene, which are used in medicine, dye, and pesticide industries. 

It can also be used as an extractant for gold and an organic solvent. 


Safety and Storage


It is toxic and can cause central nervous system poisoning and epilepsy. 

It should be stored and transported in a cool and ventilated place, away from fire, heat, oxidants, acids, and alkaline substances. 

It should be packed in iron plastic drums and kept dry.

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